Nylon PA66
Nylon PA66 (Polyamide 66), produced from the polycondensation of hexamethylenediamine and adipic acid, is the most widely used engineering polyamide and the benchmark against which other nylons are measured. With higher tensile strength, better thermal resistance, and superior stiffness compared to PA6, PA66 is the material of choice for the most demanding mechanical applications — from automotive engine compartments to industrial gear systems. Its higher melting point (260°C) and improved mechanical performance at elevated temperatures make it indispensable where PA6 falls short, though its higher moisture sensitivity requires careful drying and processing control.
Mechanical Properties
- Density: 1.15 g/cm³
- Tensile Strength: 85 MPa
- Yield Strength: 80 MPa
- Elongation at Break: 50–150%
- Flexural Modulus: 3,000 MPa
- Hardness (Rockwell): R 80 (M scale: M75)
- Heat Deflection Temperature: 90°C @ 1.8 MPa; 220°C @ 0.45 MPa
- Melting Point: 260°C
- Thermal Conductivity: 0.25 W/m·K
- Coefficient of Thermal Expansion: 8.0 × 10⁻⁵ /°C
- Water Absorption: 4.5–8.0% (equilibrium)
- Flammability Rating: V-2 (UL94)
Advantages
🟢 Higher tensile strength (85 MPa vs PA6's 80 MPa) and superior stiffness across a wider temperature range
🟢 Excellent wear resistance with low friction coefficient; performs reliably as a self-lubricating bearing material at temperatures up to 120°C
🟢 Outstanding fatigue resistance — maintains mechanical integrity through millions of loading cycles
🟢 Good chemical resistance to oils, greases, fuels, and hydrocarbon solvents
🟢 Excellent creep resistance at elevated temperatures; dimensions remain stable under sustained load
🟢 Glass fiber and carbon fiber reinforced grades available for demanding structural applications (HDT up to 250°C)
Machining & Manufacturing
| Parameter | Specification | Notes |
| Cutting Speed | Turning: 150–350 m/minMilling: 800–1,500 RPM (Ø6–Ø16 mm end mills) | - |
| Tooling | Carbide tools with sharp polished edges, 10°–15° positive rake and chip breakers; PCD/diamond-coated tools for mass production | PA66 is stickier than PA6, tools must stay sharp |
| Coolant | Emulsion or soluble oil flood coolant recommended; through-spindle coolant for deep holes & complex features | Dry machining leads to thermal softening and poor surface finish |
| Chip Control | Sticky continuous chips | Increase feed rate and use chip breakers; timely chip removal avoids re-cutting and surface damage |
| Surface Finish | Carbide tools: Ra 0.4–0.8 μmHSS tools: Ra 1.0–2.0 μm | Stable coolant and sharp tools ensure dimensional accuracy |
| Note | / | Keep machined parts dry; moisture absorption will cause dimensional variation |
Common Applications
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